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The smaller sized alkali metals are inclined to polarise the larger sized anions (the peroxide and superoxide) because of their modest dimension. This attracts the electrons in the greater complex anions toward considered one of its constituent oxygen atoms, forming an oxide ion and an oxygen atom. This will cause lithium to sort the oxide solely on reaction with oxygen at area temperature. This effect turns into drastically weaker for your bigger sodium and potassium, enabling them to kind the fewer stable peroxides. Rubidium and caesium, at the bottom of the team, are so big that even the the very least steady superoxides can type. Because the superoxide releases probably the most Electrical power when formed, the superoxide is preferentially formed with the much larger alkali metals wherever the greater elaborate anions will not be polarised. The oxides and peroxides for these alkali metals do exist, but will not form upon immediate reaction in the metal with oxygen at normal circumstances.[84] In addition, the compact dimensions of the Li+ and O2− ions contributes to their forming a steady ionic lattice framework.

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In spite of its chemical similarity, lithium generally isn't going to come about along with sodium or potassium as a result of its more compact sizing.[10]: 69  Due to its relatively small reactivity, it can be found in seawater in massive quantities; it really is approximated that lithium focus in seawater is somewhere around 0.

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Even though sodium is less reactive than potassium, this process functions for the reason that at such high temperatures potassium is much more unstable than sodium and can easily be distilled off, so the equilibrium shifts towards the ideal to provide far more potassium gasoline and proceeds Just about to completion.[10]: 74 

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Other "pseudo-alkali metals" include things like the alkylammonium cations, through which a number of the hydrogen atoms from the ammonium cation are replaced by alkyl or aryl groups. Particularly, the quaternary ammonium cations (